reactor methanol patents catalytic synthesis
FR2460707B1 - Synthesis reactor, in particular for the ...
Abstract— Recently, methanol synthesis with CO 2-rich feed has drawn a lot of attention and research is currently aimed at finding a suitable catalyst for such a task. A pseudo-homogeneous model was developed for fixed bed catalytic methanol reactor based on the reaction mechanisms and mass and energy balance equations. Our research group has been the only academic participant of the technology pool of DOE/EPRI for the development of the liquid phase methanol synthesis process (LPMeOH™). Research funding for this project was received from 1982 through 1993 from the Electric Power Research Institute (EPRI). We developed major patents involving catalyst regeneration, post-treatment, and subsequent conversion…
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A membrane reactor for methanol synthesis - ScienceDirect
A vertical reactor for catalytic exothermic and endothermic reactions, especially for the production of methanol, ammonia, synthesis gas and higher alcohols, with a jacket containing the catalyst bed and exchanger pipes which form a tube bundle running through the jacket parallel to its longitudinal axis, with a gas-permeable floor supporting the catalyst bed, as well as feed and discharge ... (57) Abstract: A method is proposed for heterogeneous exothermic synthesis of formaldehyde in the reactor with multiple connected in series adiabatic catalyst, which provides the feed to the reactor gaseous reagents containing methanol and an excess amount of oxygen, and passing the gaseous reactants through adiabatic catalytic layers, in which there is a partial oxidation of methanol.
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Process for the preparation of methanol - Haldor Topsoe A/S
A horizontal reactor for heterogeneous exothermic synthesis, in particular for methanol synthesis, of simple construction and at the same time easy maintenance, comprises a substantially cylindrical external shell (2), a plurality of beds (5a-5d) arranged horizontally and side by side in said shell and comprising a lower gas-permeable wall (6) for gas outlet and at least one chamber (10a-10c ... Methods and systems or devices for synthesis of dimethyl ether (DME) from carbon dioxide and hydrogen are provided. A high surface area hollow fiber catalytic membrane reactor such as with hollow fibers coated with a water permeable membrane material is used. The reactor also contains a bi-functional methanol synthesis component and dehydration catalyst component such that the two …
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Methyl chloride synthesis method
The concept of Multi-stage indirect cooling and Radial Flow (MRF) is ideal for designing a catalytic reactor in which an exothermic equilibrium reaction takes place. The reaction is controlled to go on along the path of the maximum reaction rate in the catalyst bed where synthesis gas flows radially in the catalyst beds from the outer side to an inner center pipe across boiler (cooling) tubes ... · An apparatus and method is disclosed for producing alcohols, particularly methanol, according to an alcohol synthesis process. The apparatus comprises a catalytic distillation reactor where reactants are fed into the catalytic distillation reactor to undergo catalytic reaction to form methanol.
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Table 2 from Simulation of methanol synthesis from ...
The present invention relates to a new process for synthesising a crystalline material comprising the zeolite MFI structure in nanocrystalline form, and which can comprise at least the following steps: i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali ... The SC methanol synthesis was performed in a conventional fixed-bed reactor where a vaporizer and an ice-cooled high-pressure trap were set upstream and downstream of the reactor, respectively, as shown in Fig. 1.The catalyst was loaded into the reactor, and then reduced at 493 K by 10% H 2 diluted in He for 1 h. After the reduction, the reactors were adjusted to the reaction condition.
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Control Structure Design for Methanol Process
The kinetics for the low-pressure synthesis of methanol from CO and H2 were studied in a small integral reactor. The mole fraction of CO was varied from 0.1 to 0.54, the total pressure from 3 to 9 ... In figure 1, reference number 1 indicates as a whole a exothermic heterogeneous catalytic synthesis reactor, in particular for methanol synthesis. The reactor 1 comprises a tiibular external shell 2 having at the top an opening 3 for input of reagent gasses, and at the bottom an opening 4 for output of the reaction products.
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heterogeneous reactor - definition - English
· Recently, methanol synthesis with CO2-rich feed has drawn a lot of attention and research is currently aimed at f inding a suitable catalyst for such a task. A pseudo-homogeneous model w as developed for f ixed bed catalytic methanol reactor based on the reaction mechanisms and mass and energy balance equations. A process for the heterogeneous exothermic synthesis of formaldehyde, in particular in a reactor (7) of the type comprising a plurality of adiabatic catalytic beds (11a-11e) connected in series, provides the step of feeding to the reactor the methanol necessary for the synthesis distributed in at least two portions, each fed to respective distinct catalytic beds (11a-11e).
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US8158074B2 - Wall system for catalytic beds of synthesis ...
Other once-through schemes attempt to remove the methanol inside the synthesis reactor, e.g., by means of a methanol permeating membrane (Struis et al., 1996), by means of a trickling liquid absorbent or trickling solid adsorbent particles (Westerterp et al., 1988, American Chemical Society, 1990), or by means of methanol condensation (Hansen and Joensen, 1991). Process and reactor for heterogeneous exothermic synthesis of formaldehyde ... A AU 56866/96A AU 5686696 A AU5686696 A AU 5686696A AU 712231 B1 B2 AU 712231B2 Authority AU Australia Prior art keywords reactor catalytic beds characterized flow catalytic Prior ... 2003-10-23 Assigned to METHANOL CASALE S.A. reassignment METHANOL CASALE S ...
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Table 1 from Simulation of methanol synthesis from ...
FR2460707B1 - Synthesis reactor, in particular for the catalytic synthesis of ammonia and methanol - Google Patents Synthesis reactor, ... methanol particular catalytic Prior art date 1979-07-13 Legal status (The legal status is an assumption and is not a legal conclusion. It is clear that a continuous removal of the products would improve dramatically the yield of a methanol synthesis reactor, reducing the amount of gas recycling and/or reducing synthesis pressure. Various attempts have been made to in situ product removal by, as an example, selective adsorption of methanol and water on a solid, trickling down a fixed bed catalytic reactor [ 3 ].
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Indian Patents. 270297:A FLUID CATALYTIC PROCESS OF ...
Of course, ‘green’ methanol synthesis is not standard methanol synthesis, proceeding according to reaction 2 rather than 1. This then means that there is a significant water level at the outlet of the reactor bed, which in turn has implications for decreased catalyst activity and lifetime. 33 This may require further modifications to catalyst structure/composition for the improvement of ... · 1. A process for preparing methanol from a synthesis gas comprising carbon monoxide, carbon dioxide and hydrogen by steps of: (a) passing the synthesis gas into a reactor containing a solid methanol conversion catalyst particles being suspended in a liquid phase of methanol and water; (b) reacting the synthesis gas in presence of the suspended catalyst at a pressure and temperature, …
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AN EXOTHERMIC HETEROGENIUS CATALYTIC SYNTHESIS …
A horizontal chemical reactor comprises at least one catalytic bed (5a-5d) arranged horizontally in the reactor and comprising a lower gas-permeable wall (6) for gas outlet, and a holding element (2) of the at least one catalytic bed. An apparatus and method is disclosed for producing alcohols, particularly methanol, according to an alcohol synthesis process. The apparatus comprises a catalytic distillation reactor where reactants are fed into the catalytic distillation reactor to undergo catalytic reaction to form methanol. Methanol production beyond the thermodynamic limit is achieved in the apparatus through use of ...
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Use of catalytic distillation reactor for methanol ...
Patents Assigned to Catalytic Distillation Technologies Selective hydrodesulfurization of FCC gasoline to below 10 ppm sulfur. ... contacting an aqueous extractant comprising water and an effluent from a methanol synthesis reactor comprising methanol and one or more of methane, water, carbon monoxide, carbon dioxide, hydrogen, ... CN1125216A discloses a process for producing dimethyl ether from methanol, comprising feeding methanol into the vaporization c6lumn to remove substances having a high boiling point and impurities, catalytically dehydrating in the presence of a composite solid acid catalyst in a multi-stags cold quenching reactor, then feeding the dehydrated product into a high performance package column for ...
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Methanol Synthesis – Sunggyu Lee, PhD
Methanol via catalytic membrane reactor to increase methanol yield: • CO 2 hydrogenation to methanol produces water • Zeolite membrane removes water by- ... hence significantly enhancing methanol yield. NG methanol synthesis catalyst (core-shell, phyllosilicate, OA-promoted Development of Highly Efficient Methanol Synthesis Process with New Catalysts 1. Introduction In the world, some 30 million tons of methanol are produced annually. The consumption of methanol as a raw material for form-aldehyde, acetic acid and other basic chemicals has been growing at a rate of about 2% a year. In recent years, since methanol ...
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Development of Highly Efficient Methanol Synthesis Process ...
The development of the methanol synthesis process from CO2 and hydrogen was studied. By introducing a reverse water-gas shift reactor (RWGS) in the methanol synthesis … Methanol unit is very important to help investigating the different operation modes of this unit and optimize that. II. MODELING OF FLUIDIZED BED REACTOR The fluidized-bed reactor has the ability to process large volumes of fluid [2]. For the catalytic cracking of …
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Patents Assigned to Catalytic Distillation Technologies ...
Recently, methanol synthesis with CO2-rich feed has drawn a lot of attention and research is currently aimed at f inding a suitable catalyst for such a task. A pseudo-homogeneous model w as developed for f ixed bed catalytic methanol reactor based on the reaction … Described here is a system ( 8; 9; 50 ) of walls for catalytic beds of reactors ( 1 ) for the heterogeneous synthesis of chemical compounds characterized in that it comprises a wall ( 14 ) of predetermined thickness in direct contact with a catalytic bed ( 7 ) for containing it, said wall having a plurality of portions ( 17 ) permeable to gases and a plurality of portions ( 19; 54; 55 ...
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